UNRAVEL THE WORLD OF ORGANIC COMPOUNDS
Product Formation
The product formation of the first ten alkanes (methane, ethane, propane, butane, pentane, hexane, heptane, octane, nonane, and decane) primarily involves combustion reactions, where these alkanes react with oxygen to produce carbon dioxide (CO2) and water (H2O) while releasing energy. This feed also includes other chemical reactions that will lead to the product formation of alkanes.
Combustion Reactions
Combustion is a chemical reaction in which a substance, in the presence of oxygen (usually from the air), rapidly burns and produces heat, light, and typically forms carbon dioxide (CO2) and water (H2O) as products.
​
Note: These are balanced chemical equations.
​
Methane (CH4) combustion:
CH4(g) + 2O2(g) -> CO2(g) + 2H2O(g)
​Ethane (C2H6) combustion:
2C2H6(g) + 7O2(g) -> 4CO2(g) + 6H2O(g)
Propane (C3H8) combustion:
C3H8(g) + 5O2(g) -> 3CO2(g) + 4H2O(g)
Butane (C4H10) combustion:
2C4H10(g) + 13O2(g) -> 8CO2(g) + 10H2O(g)
Pentane (C5H12) combustion:
C5H12(g) + 8O2(g) -> 5CO2(g) + 6H2O(g)
Hexane (C6H14) combustion:
2C6H14(g) + 19O2(g) -> 12CO2(g) + 14H2O(g)
Heptane (C7H16) combustion:
C7H16(g) + 11O2(g) -> 7CO2(g) + 8H2O(g)
Octane (C8H18) combustion:
2C8H18(g) + 25O2(g) -> 16CO2(g) + 18H2O(g)
Nonane (C9H20) combustion:
C9H20(g) + 14O2(g) -> 9CO2(g) + 10H2O(g)
Decane (C10H22) combustion:
2C10H22(g) + 31O2(g) -> 20CO2(g) + 22H2O(g)
Halogenation
Alkanes can undergo halogenation reactions when exposed to halogens like chlorine (Cl2) or bromine (Br2). In these reactions, one or more hydrogen atoms in the alkane are replaced by halogen atoms.
-
For example, in the chlorination of methane:
-
CH4(g) + Cl2(g) -> CH3Cl(g) + HCl(g)
-
Further chlorination can occur, leading to the formation of products like CH2Cl2, CHCl3, and CCl4.
-
Pyrolysis or Crackling
Alkanes can be cracked at high temperatures to break longer chains into shorter ones. This process is commonly used in the petroleum industry to produce smaller hydrocarbons, such as gasoline and diesel, from heavier fractions.
​
-
For instance, in cracking hexane (C6H14):
-
C6H14(g) -> C3H8(g) + C3H6(g)
-
Dehydrogenation
In this reaction, alkanes lose hydrogen atoms to form alkenes. This is often used to produce olefins (alkenes) from alkanes.
​
-
For example, the dehydrogenation of propane:
-
C3H8(g) -> C3H6(g) + H2(g)
-
Alkylation
Alkanes can be alkylated, often in the presence of a strong base, to introduce alkyl groups. This is used in the synthesis of more complex organic molecules.
​
-
Alkylation of methane to produce methyl chloride:
-
CH4(g) + CH3Cl(g) -> C2H6(g) + HCl(g)
-